Analysis of the association of parameters in the formation of ultrafine fibers from PEI and PMMA
Objective: The aim of the study was to fabricate and morphologically characterize ultrafine Polyetherimide fibers (PEI) associated with Polymethylmethacrylate (PMMA) – PP (group formed by the association of PEI with PMMA), produced by the electrospinning process. Material and Methods: A solution of PEI (0.562 g) + PMMA (0.377 g) dissolved in 2.5 mL of chloroform, 0.85 mL of Dimethylformamide (DMF) and 0.85 mL of 126.96.36.199 Tetrachloroethane (TCE) was prepared. For the electrospinning process, different continuous voltages (10 to 18 kV) and two different distances (8 and 12 cm) between the needle tip and the collecting apparatus were used, giving rise to 6 distinct groups of ultrafine fibers (PP 1 to 6) that were observed in Scanning Electron Microscopy to check for defects and calculate the average diameter of the fibers. Results: The best parameter, the parameter that was most effective for the production of fibers, observed was subjected to Energy Dispersion X-ray Spectroscopy (EDS), X-ray Diffraction (XRD) and Contact Angle Analysis tests. The data were analyzed using the ANOVA and Tukey test (p <0.05). From the comparative analysis of the pre-established parameters, the pattern of PP4 ultrafine fibers was shown to be more effective. Conclusion: The PP4 standard (13 kV – 12 cm) had an average diameter of 0.37 µm. An adequate parameter to electrospinning was able to produce ultrafine fibers of PMMA/PEI.
Polymethylmethacrylate; Scanning electron microscopy; Polyetherimide; Electrospinning process.
Costa AKF, da Silva LH, Saavedra GSFA, Paes TJA, Borges ALS. Flexural strength of four adhesive fixed dental prostheses of composite resin reinforced with glass fiber. J Adhes Dent. 2012;
Ellakwa AE, Shortall AC, Shehata MK, Marquis PM. Influence of bonding agent composition on flexural properties of an ultra-high molecular weight polyethylene fiber-reinforced composite. Oper Dent. 2002;
Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol. 2003;63(15):2223–53.
Sun W, Cai Q, Li P, Deng X, Wei Y, Xu MM, et al. Post-draw PAN-PMMA nanofiber reinforced and toughened Bis-GMA dental restorative composite. Dent Mater. 2010;
Wang W, Ciselli P, Kuznetsov E, Peijs T, Barber AH. Effective reinforcement in carbon nanotube-polymer composites. Philos Trans R Soc A Math Phys Eng Sci. 2008;
Uyar T, Çökeliler D, Do?an M, Koçum IC, Karatay O, Denkba? EB. Electrospun nanofiber reinforcement of dental composites with electromagnetic alignment approach. Mater Sci Eng C. 2016;62:762–70.
Vidotti HA. O papel da concentração de nanofibras e da composição da matriz resinosa nas propriedades flexurais de compósitos experimentais baseados em nanofibras. 2015;(Tese (Doutorado)-Faculdade de Odontologia de Bauru. Universidade de São Paulo):113p.
Borges ALS, Münchow EA, de Oliveira Souza AC, Yoshida T, Vallittu PK, Bottino MC. Effect of random/aligned nylon-6/MWCNT fibers on dental resin composite reinforcement. J Mech Behav Biomed Mater. 2015;
Dzenis Y. Spinning continuous fibers for nanotechnology. Science. 2004.
Reneker DH, Yarin AL. Electrospinning jets and polymer nanofibers. Polymer. 2008.
Johnson RO, Burlhis HS. Polyetherimide: A new high-performance thermoplastic resin. J Polym Sci Polym Symp [Internet]. 2007;70(1):129–43. Available from: http://doi.wiley.com/10.1002/polc.5070700111
Liu G, Ding J, Qiao L, Guo A, Dymov BP, Gleeson JT, et al. Polystyrene-block-poly(2-cinnamoylethyl methacrylate) Nanofibers—Preparation, Characterization, and Liquid Crystalline Properties. Chem - A Eur J. 1999;
Mano EB. Polímeros Como Materiais de Engenharia. 3a. Edgard B, editor. São Paulo; 1991.
Tian M, Gao Y, Liu Y, Liao Y, Xu R, Hedin NE, et al. Bis-GMA/TEGDMA dental composites reinforced with electrospun nylon 6 nanocomposite nanofibers containing highly aligned fibrillar silicate single crystals. Polymer (Guildf). 2007;
Reiter J, Krejza O, Sedla?íková M. Electrochromic devices employing methacrylate-based polymer electrolytes. Sol Energy Mater Sol Cells. 2009;
De Souza JR, Sato TP, Borges ALS. Scaffold architecture for dental biomaterials: influence of process parameters on the structural morphology of chitosan electrospun fibers. Brazilian Dent Sci. 2017;
Yuan XY, Zhang YY, Dong C, Sheng J. Morphology of ultrafine polysulfone fibers prepared by electrospinning. Polym Int. 2004;
Chang FC, Chan KK, Chang CY. The effect of processing parameters on formation of lignosulfonate fibers produced using electrospinning technology. BioResources. 2016;
Lu H, Lee YK, Oguri M, Powers JM. Properties of a Dental Resin Composite with a Spherical Inorganic Filler. Oper Dent [Internet]. 2006;31(6):734–40. Available from: http://www.jopdentonline.org/doi/10.2341/05-154
Miyoshi T, Toyohara K, Minematsu H. Preparation of ultrafine fibrous zein membranes via electrospinning. Polym Int. 2005;
Bunaciu AA, Udri?tioiu E gabriela, Aboul-Enein HY. X-Ray Diffraction: Instrumentation and Applications. Critical Reviews in Analytical Chemistry. 2015.
Kaur K, Singh KJ, Anand V, Bhatia G, Kaur R, Kaur M, et al. Scaffolds of hydroxyl apatite nanoparticles disseminated in 1, 6-diisocyanatohexane-extended poly(1, 4-butylene succinate)/poly(methyl methacrylate) for bone tissue engineering. Mater Sci Eng C. 2017;
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